1. Home
  2. Class 11
  3. Physics
  4. Mechanical Properties of Fluids
In this chapter
NotesShala Class 11 · Physics
Chapter09

Mechanical Properties of Fluids

Hydrostatics · Surface Tension · Hydrodynamics and Viscosity

Reading key Definition Note Remember Derivation Strategy Formulas sit on graph paper · coloured words are the key terms
01
Part 1

Hydrostatics

Fluids give very little resistance to a shear stress. Even a very small shear stress changes their shape. This is the key property of fluids. In this part we study fluids at rest.

1.1Thrust

Take a fluid kept in a container. Its molecules are always in random motion. They move because of their thermal velocities.

So the molecules keep hitting the walls and bouncing back. In each hit, the momentum of a molecule changes in the direction normal to the wall. This normal momentum passes on to the wall.

thrust thrust liquid
The liquid pushes normally on the walls and the base
Definition

The thrust of a fluid is the normal momentum that its molecules give to the container walls in unit time.

1.2Liquid in Equilibrium

Concept

For a liquid in equilibrium, the net force on it always acts perpendicular to its surface. The proof is given below.

Setup — Given Information
  • A liquid is kept in a vessel. It is at rest.
  • Suppose the net force FF makes an angle θ\theta with the direction parallel to the surface.
  • Split FF into two components, as in the figure.
liquid surface θ F cos θ F sin θ F
FF has a part Fcos⁡θF\cos\theta along the surface and a part Fsin⁡θF\sin\theta normal to it
iTangential Component

Fcos⁡θF\cos\theta acts along (parallel to) the liquid surface.

iiNormal Component

Fsin⁡θF\sin\theta acts perpendicular to the liquid surface.

Derivation

The liquid is at rest, so it does not flow. Hence the part of the force along the surface must be zero:

  1. Fcos⁡θ=0…(i)F\cos\theta = 0 \qquad \text{…(i)}
  2. F≠0, so cos⁡θ=0  ⇒  θ=90∘F \neq 0, \text{ so } \cos\theta = 0 \;\Rightarrow\; \theta = 90^\circ
Result

When a liquid is in equilibrium at rest, the net force always acts perpendicular to the liquid surface.

1.3Pressure

Definition

The pressure at a point in a liquid at rest is the thrust (normal force) that the liquid exerts per unit area around that point.

Let a total force FF act normally on a flat area AA. Then the pressure is:

Pressure p=thrustarea=FAp = \dfrac{\text{thrust}}{\text{area}} = \dfrac{F}{A}

where, FF = total normal force on the surface, AA = area on which it acts

CGS Unit

dyne cm−2\text{dyne cm}^{-2}

SI Unit

N m−2\text{N m}^{-2} (pascal)

Dimensions

[ML−1T−2][\mathrm{M L^{-1} T^{-2}}]

Good to know
One Pascal (1 Pa)

A pressure of 1 N m−21\ \text{N m}^{-2} is called 1 pascal. The unit is named after the French scientist Blaise Pascal (1623–1662). He did the first major studies of pressure in fluids.

1 Pa=1 N m−2=10 dyne cm−21\ \text{Pa} = 1\ \text{N m}^{-2} = 10\ \text{dyne cm}^{-2}
Atmosphere (atm)

The atmosphere (atm) is another common unit of pressure. 1 atm is the pressure of the air at sea level.

1 atm=1.013×105 Pa1\ \text{atm} = 1.013 \times 10^{5}\ \text{Pa}
Force Not Spread Evenly

If the force is not uniform, the pressure is different at different points. Let a small normal force ΔF\Delta F act on a small area ΔA\Delta A around a point. Then:

p=lim⁡ΔA→0ΔFΔA=dFdAp = \displaystyle\lim_{\Delta A \to 0}\dfrac{\Delta F}{\Delta A} = \dfrac{dF}{dA}
Note
Pressure is a Scalar

At a given point in a liquid, the pressure has the same value in every direction. So no definite direction goes with pressure. Hence pressure is a scalar quantity.

Practical Applications of Pressure

For the same force, a smaller area gives a larger pressure.

iKnife

A sharp knife cuts more easily than a blunt knife. Its edge has a very small area, so the pressure is large.

iiCamel

A camel has broad feet. So it presses less on sand and walks easily. A man finds walking on sand difficult.

iiiRailway Tracks

Tracks rest on large wooden or iron sleepers. They spread the weight and reduce the pressure on the ground.

ivNeedle

A sharp needle goes into the skin easily, but a dull one does not. This happens even when we apply the same force.

Good to know
Ice-skating

The sharp metal edges of skates press hard on the ice. This pressure melts a little ice under them. The tiny water drops act like rigid ball bearings. So the skater glides smoothly.

1.4Density and Relative Density

Definition

The density of a substance is its mass per unit volume. It is written as ρ\rho.

Let a substance have mass MM and volume VV. Then its density is:

Density ρ=MV\rho = \dfrac{M}{V}

where, MM = mass of the substance, VV = its volume

SI unit of densitykg m−3\text{kg m}^{-3}
Dimensions of density[ML−3][\mathrm{M L^{-3}}]
Relative Density (Specific Gravity)
Definition

The relative density (also called specific gravity) of a substance is its density divided by the density of water at 4°C.

Relative Density Relative density=Density of substanceDensity of water at 4∘C\text{Relative density} = \dfrac{\text{Density of substance}}{\text{Density of water at } 4^\circ\text{C}}
Unit and Nature

It is a ratio of two densities. So it has neither a unit nor dimensions. It is a positive scalar.

Water at 4°C

Water is densest at 4°C. Its density then is 1000 kg m−31000\ \text{kg m}^{-3}.

1.5Pascal's Law

Law

Pascal's law: In a fluid at rest, the pressure is the same at all points that are at the same height.

This was first noticed by the French scientist Blaise Pascal.

Proof of Pascal's Law

The proof uses two ideas:

iNormal Force

In a fluid at rest, the force on any layer is normal to it.

iiNewton's First Law

The small element of fluid is in equilibrium. So the forces on it balance.

Setup — Given Information
  • Take a tiny element ABC-DEF inside a fluid at rest. It has the shape of a right-angled prism.
  • The prism is so small that all its parts are at the same depth. So gravity has the same effect at all its points.
  • Pressures pap_a, pbp_b, pcp_c act on the faces BEFC, ADFC and ADEB.
  • The normal forces on these faces are FaF_a, FbF_b, FcF_c. Their areas are AaA_a, AbA_b, AcA_c.
θ Fc Fa Fb ABC DEF θ Fb sin θ Fb cos θ Fb Components of Fb
Tiny prism ABC-DEFABC\text{-}DEF in a fluid at rest (left) and the two components of FbF_b (right)
Derivation

In the right triangle ABC, ∠ACB=θ\angle ACB = \theta. Resolve the normal forces along the horizontal and the vertical:

  1. Fbsin⁡θ=FcandFbcos⁡θ=Fa…(i)F_b\sin\theta = F_c \quad\text{and}\quad F_b\cos\theta = F_a \qquad \text{…(i)}
  2. From the geometry of the prism, the face areas are related as:
    Absin⁡θ=AcandAbcos⁡θ=Aa…(ii)A_b\sin\theta = A_c \quad\text{and}\quad A_b\cos\theta = A_a \qquad \text{…(ii)}
  3. Divide each force equation in (i) by the matching area equation in (ii):
    Fbsin⁡θAbsin⁡θ=FcAcandFbcos⁡θAbcos⁡θ=FaAa\dfrac{F_b\sin\theta}{A_b\sin\theta} = \dfrac{F_c}{A_c} \quad\text{and}\quad \dfrac{F_b\cos\theta}{A_b\cos\theta} = \dfrac{F_a}{A_a}
  4. ∴ FaAa=FbAb=FcAc\therefore\ \dfrac{F_a}{A_a} = \dfrac{F_b}{A_b} = \dfrac{F_c}{A_c}
Result of Pascal's Law pa=pb=pcp_a = p_b = p_c

since p=FAp = \dfrac{F}{A}, all three faces feel the same pressure

Note

So a fluid at rest presses on a body inside it equally in all directions. No direction can be given to this pressure. Hence pressure is not a vector quantity.

1.6Variation of Pressure with Depth

Setup — Given Information
  • A fluid of density ρ\rho is at rest in a cylindrical vessel.
  • Two points A and B are a vertical distance hh apart.
  • Imagine a cylinder of fluid with cross-section area AA. Point A is on its top face and point B on its bottom face.
A B F1 F2 mg h
Imaginary fluid cylinder between A (top) and B (bottom)
Derivation
  1. The weight of the fluid cylinder acts downward:
    w=mg=volume×density×g=Ahρg[∵V=A×h]w = mg = \text{volume} \times \text{density} \times g = Ah\rho g \qquad [\because V = A \times h]
  2. The fluid is at rest. The horizontal forces cancel. So the total downward force equals the total upward force:
    F1+w=F2⇒F2−F1=wF_1 + w = F_2 \quad\Rightarrow\quad F_2 - F_1 = w

    Here F1F_1 acts downward on the top face and F2F_2 acts upward on the bottom face.

  3. Write each force as pressure × area:
    p2A−p1A=Ahρg⇒A(p2−p1)=A(hρg)p_2 A - p_1 A = Ah\rho g \quad\Rightarrow\quad A(p_2 - p_1) = A(h\rho g)
Pressure Difference with Depth p2−p1=hρgp_2 - p_1 = h\rho g
Note

This pressure difference depends on three things: the vertical height between A and B, the density ρ\rho of the fluid, and the value of gg.

Now move point A up to the free surface, which is open to the air. Put p1=pap_1 = p_a (atmospheric pressure) and p2=pp_2 = p:

Pressure at a Depth h p=pa+hρgp = p_a + h\rho g

At a depth hh below an open liquid surface, the pressure is more than the atmospheric pressure by hρgh\rho g.

Definition

The gauge pressure at a point is the total pressure there minus the atmospheric pressure.

p−pa=hρgp - p_a = h\rho g

1.7Hydrostatic Paradox

Vessels A, B and C have different shapes. They are joined at the bottom. Each one holds a different amount of liquid. Yet the liquid level is the same in all three. This is called the hydrostatic paradox.

same level CAB
Vessels A, B and C hold different amounts of liquid, but the level is the same
Concept
Hydrostatic Paradox

Liquid pressure depends only on how tall the liquid column is. The shape of the vessel does not matter.

Liquid pressure and the height of the liquid columnDepends on it
Liquid pressure and the shape of the vesselDoes not depend

1.8Atmospheric Pressure and Gauge Pressure

Definition

The layer of air around the Earth is called the Earth's atmosphere. The pressure exerted by this air is called the atmospheric pressure (pap_a). It equals the force of the air column on each unit area of the Earth's surface.

Atmospheric pressure at sea level = 1 atmosphere (1 atm)≈1.013×105 N m−2\approx 1.013 \times 10^{5}\ \text{N m}^{-2}

The atmosphere exerts a very large pressure. The methods below show this.

Mercury Barometer
  • The Italian scientist Evangelista Torricelli (1608–1647) made the first instrument to measure atmospheric pressure. It is called a barometer.
  • Fill a long glass tube (one end closed) with mercury. Then turn it upside down into a trough of mercury.
  • The mercury in the tube settles about 76 cm higher than the mercury in the trough.
near vacuum h ≈ 76 cm pa A B mercury
Mercury barometer: A and B are at the same level
Note

Above the mercury column, the tube holds only mercury vapour. Its pressure is very small, so we neglect it.

Points A and B are at the same level, so their pressures are equal. So the atmospheric pressure equals the pressure of the mercury column of height hh:

Atmospheric Pressure from a Barometer pa=hρgp_a = h\rho g

where, hh = height of the mercury column, ρ\rho = density of mercury

Example

Put h=0.76h = 0.76 m, ρ=13.6×103 kg m−3\rho = 13.6 \times 10^{3}\ \text{kg m}^{-3} and g=9.8 m s−2g = 9.8\ \text{m s}^{-2}:

pa=0.76×13.6×103×9.8=1.013×105 N m−2=1.013×105 Pap_a = 0.76 \times 13.6 \times 10^{3} \times 9.8 = 1.013 \times 10^{5}\ \text{N m}^{-2} = 1.013 \times 10^{5}\ \text{Pa}

This value is the sea-level atmospheric pressure.

Pressure of a 1 mm column of mercury1 torr
Open Tube Manometer

We use an open tube manometer to measure pressure differences. The figure shows the set-up.

  • It is a U-shaped tube with some liquid in it.
  • One arm is open to the air. The other arm is joined to a vessel (flask) whose pressure we want to find.
p vessel pa A B h liquid
Open tube manometer: A and B are at the same level
Low-density liquid (oil or water)Small pressure differences
High-density liquid (mercury)Large pressure differences
Note
Pressure Relation

Points A and B are at the same level in the same liquid. So by Pascal's law, the pressure pp at A equals the pressure at B:

p=pA=pB=pa+hρgp = p_A = p_B = p_a + h\rho g
Absolute Pressure and Gauge Pressure
Absolute Pressure

Absolute pressure is the full, actual pressure pp at a point.

Gauge Pressure

The gauge pressure is the absolute pressure at a point minus the atmospheric pressure.

Gauge Pressure pg=p−pa=hρgp_g = p - p_a = h\rho g

So the gauge pressure is proportional to hh.

Good to know

Many pressure gauges read the gauge pressure directly. Examples: a gauge that checks tyre pressure, and a blood pressure gauge (sphygmomanometer).

Height of the Atmosphere

Standard atmospheric pressure is 1.013×1051.013 \times 10^{5} Pa. Suppose the air had a uniform density ρ=1.29 kg m−3\rho = 1.29\ \text{kg m}^{-3} all the way up. Let hh be the height of the air column that gives this pressure. Then:

hρg=1.013×105  ⇒  h=1.013×105ρg=1.013×1051.29×9.8 mh\rho g = 1.013 \times 10^{5} \;\Rightarrow\; h = \dfrac{1.013 \times 10^{5}}{\rho g} = \dfrac{1.013 \times 10^{5}}{1.29 \times 9.8}\ \text{m}
Height of the Atmosphere (uniform density) h≈8.01×103 m≈8 kmh \approx 8.01 \times 10^{3}\ \text{m} \approx 8\ \text{km}
Note

In reality, the density of air falls with height. The value of gg also falls. In fact, the atmosphere reaches a height of nearly 100 km.

Different Units of Pressure
iAtmosphere (atm)

It equals the pressure of a mercury column 76 cm high, at 0°C, at 45° latitude and at mean sea level.

iiBar and Millibar

Used in meteorology (weather science).

1 bar=105 Pa=106 dyne cm−21\ \text{bar} = 10^{5}\ \text{Pa} = 10^{6}\ \text{dyne cm}^{-2}
1 mbar=10−3 bar=100 Pa1\ \text{mbar} = 10^{-3}\ \text{bar} = 100\ \text{Pa}
iiiTorr

Named after Torricelli.

1 torr=1 mm of Hg=133 Pa1\ \text{torr} = 1\ \text{mm of Hg} = 133\ \text{Pa}
Unit Relation 1 atm=1.013 bar=760 torr1\ \text{atm} = 1.013\ \text{bar} = 760\ \text{torr}
Note
  • If the atmospheric pressure falls by 10 mm of Hg or more, a storm is likely on its way.
  • Gauge pressure can be positive (p>pap > p_a) or negative (p<pap < p_a).
  • In inflated tyres and in the human circulatory system, the absolute pressure is more than the atmospheric pressure. So the gauge pressure is positive. It is called over pressure.
  • When we suck a drink through a straw, the pressure in our lungs is less than the atmospheric pressure. So the gauge pressure there is below zero.
Tyres and blood vessels (p>pap > p_a)Positive gauge pressure
Drinking with a straw (p<pap < p_a)Negative gauge pressure

1.9Pascal's Law for Transmission of Fluid Pressure

Law

Pascal's law (transmission of pressure): Apply an external pressure to any part of a fluid that is enclosed in a vessel and at rest. The fluid passes this pressure on to every part of it. The pressure reaches every point without any loss and acts equally in all directions.

Pressure applied to one part of a confined fluidPassed equally in all directions
Note

This law has many uses in daily life. Some of them are given in the next topic.

1.10Applications of Pascal's Law

(i) Hydraulic Lift
Concept

A hydraulic lift is used to raise heavy loads. It is based on Pascal's law and works as a force multiplier.

Setup — Given Information
  • Two cylinders C1C_1 and C2C_2 are joined by a pipe E.
  • Each has a tight, frictionless piston. The piston areas are different.
  • A liquid fills the cylinders and the pipe.
Load f F a A C1 C2 E
Hydraulic lift: ff on area aa, FF on area AA
Derivation
  1. Push the smaller piston (area aa) down with a force ff. The pressure on the liquid is:
    p=fap = \dfrac{f}{a}
  2. By Pascal's law, this pressure reaches the larger piston (area AA). So the upward force on it is:
    F=p×A=fa×A=Aa×fF = p \times A = \dfrac{f}{a} \times A = \dfrac{A}{a} \times f
Upward Force on the Larger Piston F=Aa fF = \dfrac{A}{a}\,f
Since A>aA > a, we get F>fF > f. A small force gives a large forceHeavy load lifted
(ii) Hydraulic Brakes

Hydraulic brakes also work on Pascal's law.

Construction
  • A tube T is filled with brake oil.
  • One end of T goes to the wheel cylinder. It has two pistons, P1P_1 and P2P_2. These pistons are joined to the brake shoes S1S_1 and S2S_2.
  • The other end of T goes to the master cylinder. A lever system links its piston P to the brake pedal.
To other wheels Tube T P Lever system Master cylinder Brake pedal spring P1 P2 S1 S2 Wheel cylinder Brake shoes
Hydraulic brakes: master cylinder (PP), tube TT, wheel cylinder (P1P_1, P2P_2) and brake shoes (S1S_1, S2S_2)
Cross-section area: wheel cylinder compared with master cylinderWheel cylinder is larger
Working of Hydraulic Brakes
  • Pedal pressed: When the driver presses the brake pedal, the lever system pushes piston P. By Pascal's law, the pressure reaches pistons P1P_1 and P2P_2.
  • Shoes pushed out: Pistons P1P_1 and P2P_2 push the brake shoes apart. The shoes press on the inner rim of the wheel and slow down the wheel.
  • Force multiplied: The wheel-cylinder pistons have a larger area than piston P. So a small force on the pedal gives a large thrust on the wheels. This makes the brakes work.
  • Pedal released: When the driver releases the pedal, a spring pulls the shoes back from the rim to their normal place. This pushes the oil back into the master cylinder.
  • All wheels: The master cylinder is joined by tubes to all the wheels. So equal pressure reaches every wheel.
  • Result: So a small force on the pedal puts a far larger force on the drums of the wheels. This helps the driver keep the vehicle under control.

1.11Buoyancy

Definition

When a body is partly or fully immersed in a fluid at rest, it pushes aside (displaces) some fluid. The fluid then pushes the body upward.

This upward force on the body is called the upthrust or buoyant force. The effect is called buoyancy.

Where the Weight Acts

The weight acts at the centre of gravity of the body.

Where the Upthrust Acts

The buoyant force acts through the centre of buoyancy. This point is the centre of gravity of the displaced liquid.

1.12Archimedes' Principle

Principle

Archimedes' principle gives the size of the buoyant force. A body fully or partly immersed in a liquid at rest feels an upthrust. The upthrust equals the weight of the liquid that the immersed part of the body pushes aside (displaces). This force passes through the centre of gravity of the fluid displaced.

Proof of Archimedes' Principle
Setup — Given Information
  • A cylinder of height hh and area AA is immersed in a fluid.
  • Upward force F2F_2 on its bottom is larger than downward force F1F_1 on its top.
  • p1p_1, p2p_2 = pressures on the top and bottom faces.
F1 F2 h
Forces on an immersed body
Derivation
  1. The net upward force of the fluid on the body is:
    F2−F1=(p2−p1)AF_2 - F_1 = (p_2 - p_1)A
  2. From the pressure difference with depth:
    p2−p1=hρgp_2 - p_1 = h\rho g
  3. So the net upward force is:
    (p2−p1)A=hρgA=mg[∵m=Aρh](p_2 - p_1)A = h\rho g A = mg \qquad [\because m = A\rho h]

    Here ρ\rho = density of the fluid and AA = cross-section area of the body. So mm is the mass of the fluid displaced.

Result

The fluid pushes the body up with a force equal to the weight of the fluid it displaces, that is, mgmg.

Laws of Floatation

A body placed in a fluid can behave in three ways. Let WbW_b be its weight and FBF_B the upthrust when it is fully immersed.

iWeight > Upthrust

Wb>FBW_b > F_B: the body sinks.

iiWeight = Upthrust

Wb=FBW_b = F_B: the weight is just balanced. The body floats fully immersed.

iiiWeight < Upthrust

Wb<FBW_b < F_B: the body floats partly immersed.

Law
Law of Floatation

Let a floating body have total volume VbV_b. Let a part VpV_p of it be under the fluid. At equilibrium, the weight of the body equals the weight of the fluid it displaces:

Vb ρb g=Vp ρf gV_b\,\rho_b\,g = V_p\,\rho_f\,g
Law of Floatation ρbρf=VpVb\dfrac{\rho_b}{\rho_f} = \dfrac{V_p}{V_b}

where, ρb\rho_b = density of the body, ρf\rho_f = density of the fluid

02
Part 2

Surface Tension

2.1Surface Tension

Concept

A liquid at rest has some extra potential energy at its free surface. Because of this, the surface tries to keep its area as small as possible. So the surface acts like a stretched membrane.

e.g. Steel is denser than water. Still, a steel needle can be made to float on water. The water surface acts like a stretched elastic sheet and holds the needle up. This property is called surface tension.

Imagine a line AB drawn on a liquid surface. The surface on each side pulls this line. The two pulls are equal and opposite. They act perpendicular to the line. So the line stays in equilibrium.

The pull is proportional to the length of the line. Let ll be its length and FF the force on either side. Then:

F∝l  ⇒  F=Sl  ⇒  S=FlF \propto l \;\Rightarrow\; F = Sl \;\Rightarrow\; S = \dfrac{F}{l}
A B l F F
Equal and opposite pulls FF on the line ABAB
Definition

Surface tension (SS) is the force per unit length on an imaginary line drawn on the free surface of a liquid. The force acts at right angles to the line and lies along the surface (it is tangential). Surface tension is a scalar quantity.

Surface Tension S=Fl=ForceLengthS = \dfrac{F}{l} = \dfrac{\text{Force}}{\text{Length}}
SI Unit

N m−1\text{N m}^{-1}

CGS Unit

dyne cm−1\text{dyne cm}^{-1}

Dimensions

[MLT−2][L]=[ML0T−2]\dfrac{[\mathrm{MLT^{-2}}]}{[\mathrm{L}]} = [\mathrm{ML^{0}T^{-2}}]

Factors Affecting Surface Tension
1 · Temperature

Surface tension falls as the temperature rises. It becomes zero at a certain temperature. This is called the critical temperature of the liquid.

For small changes in temperature, it falls almost linearly:   St=S0(1−αt)\;S_t = S_0(1 - \alpha t)

Here StS_t = surface tension at t∘t^\circC, S0S_0 = surface tension at 0∘0^\circC and α\alpha = temperature coefficient of surface tension.

  • Soup tastes nicer when hot than when cold. Hot soup has a lower surface tension, so it spreads over more of the tongue.
2 · Impurities

Adding impurities changes surface tension a lot.

  • Sodium chloride dissolves easily (it is highly soluble). Adding it raises the surface tension of water.
  • Phenol or soap dissolves only a little (sparingly soluble). Adding it lowers the surface tension of water.
Detergents and Surface Tension
  • Detergents used to wash dirty clothes show a common use of surface tension.
  • Oily dirt on clothes does not get wet by plain water. So water by itself cannot remove the dirt.
  • A detergent molecule sticks to both water and dirt molecules. So washing carries the dirt away.
Applications of Surface Tension
iRound Drops

Rain drops, and drops of mercury on a glass plate, are spherical.

iiBrush Hair

The hair of a shaving or painting brush spread out in water. They cling together as soon as the brush is taken out.

iiiFloating Needle

A greased needle, laid gently on water, stays afloat.

ivOil Drops

An oil drop spreads out on cold water. On hot water, it keeps its shape.

Measuring the Surface Tension of a Liquid

A thin, flat glass plate is held vertical. It hangs from one arm of a balance. Weights on the other arm balance it. A vessel of the liquid is kept below the plate.

The vessel is raised until the liquid just touches the plate. Surface tension then pulls the plate down. Now weights are added until the plate just leaves the liquid. Let this extra weight be mgmg. The liquid touches both faces of the plate edge, so the total length is 2l2l.

glass plate l weights mg
A glass plate pulled down by surface tension, balanced by weights
Surface Tension (Plate Method) S=mg2lS = \dfrac{mg}{2l}

where, mm = extra mass needed, ll = length of the plate edge

2.2Surface Energy

Definition

A liquid surface always tries to shrink to the smallest possible area. To increase this area at constant temperature, work must be done. This work is stored in the surface film as potential energy.

The surface energy is this potential energy stored per unit area of the surface film. In other words, it is the work needed to increase the surface area by one unit.

Surface Energy Surface energy=Work done in increasing the surface areaIncrease in surface area\text{Surface energy} = \dfrac{\text{Work done in increasing the surface area}}{\text{Increase in surface area}}

SI unit of surface energy: J m−2\text{J m}^{-2}

How Surface Energy Relates to Surface Tension
Setup — Given Information
  • Take a rectangular wire frame PQRS. Its side QR can slide.
  • Dip the frame in soap solution to form a soap film on it. Surface tension pulls the wire QR inward.
  • QR is pulled outward through a small distance against this force. This stretches the film.
Derivation
  1. Surface tension is force per unit length. A soap film has two surfaces, so the total length on QR is 2l2l:
    S=F′2l⇒F′=S×2lS = \dfrac{F'}{2l} \quad\Rightarrow\quad F' = S \times 2l
  2. An outside force FF (equal to F′F') moves QR very slowly through a distance xx. The work done is:
    W=Force×distance=S×2l×xW = \text{Force} \times \text{distance} = S \times 2l \times x
  3. The film has two sides, so its area grows by 2l×x2l \times x. Hence:
    Surface energy=Work doneSurface area=S⋅2lx2lx=S\text{Surface energy} = \dfrac{\text{Work done}}{\text{Surface area}} = \dfrac{S \cdot 2lx}{2lx} = S
2Sl F l PS QR (a) Equilibrium 2Sl F x l PS QR Q′R′ (b) Stretched by x
Soap film on frame PQRSPQRS: (a) in equilibrium, (b) after QRQR is pulled out by xx
Surface Energy and Surface Tension Surface energy=S\text{Surface energy} = S

Surface energy and surface tension of a liquid have the same numerical value.

2.3Angle of Contact

Definition

Near the place where a liquid touches another medium, the liquid surface is curved. The angle of contact (θ\theta) is the angle that the tangent to the liquid surface, drawn at the point of contact, makes with the solid surface inside the liquid.

The angle of contact depends on these factors:

iMaterials

The nature of the solid and the liquid in contact.

iiCleanliness

How clean the surfaces in contact are.

iiiMedium

The medium (like air) above the liquid surface.

ivTemperature

How hot the liquid is (its temperature).

e.g. Water forms drops on a lotus leaf. But it spreads out on a clean plastic plate.

Three surfaces meet at the line of contact. Each pair has its own surface tension:

  • SsaS_{sa}: surface tension between the solid and air
  • SlaS_{la}: surface tension between the liquid and air
  • SslS_{sl}: surface tension between the solid and liquid
θ Sla Ssa O Ssl (a) θ > 90° θ Sla Ssa O Ssl (b) θ < 90°
Drops with (a) an obtuse and (b) an acute angle of contact θ\theta

At the line of contact, the three surface forces are in equilibrium. Split SlaS_{la} into two parts: Slacos⁡θS_{la}\cos\theta along the solid surface and Slasin⁡θS_{la}\sin\theta perpendicular to it. For balance along the solid, we get:

Angle of Contact Ssa=Ssl+Slacos⁡θ⇒cos⁡θ=Ssa−SslSlaS_{sa} = S_{sl} + S_{la}\cos\theta \quad\Rightarrow\quad \cos\theta = \dfrac{S_{sa} - S_{sl}}{S_{la}}

So there are two cases:

iSsl>SsaS_{sl} > S_{sa}

cos⁡θ\cos\theta is negative, so θ>90∘\theta > 90^\circ (obtuse). Such liquids do not wet the solid.

e.g. Mercury on glass: θ>90∘\theta > 90^\circ, non-wetting.

iiSsl<SsaS_{sl} < S_{sa}

cos⁡θ\cos\theta is positive, so θ<90∘\theta < 90^\circ (acute). Such liquids wet the solid.

e.g. Water on glass: θ<90∘\theta < 90^\circ, wetting.

2.4Excess Pressure Inside Drops and Bubbles

Excess Pressure: Liquid Drop
Setup — Given Information
  • Take a liquid drop of radius RR. It is a sphere. Its surface tension is SS.
  • Because it is curved, the pressure inside is more than outside. This excess pressure pp acts normally outward.
  • p=pi−pop = p_i - p_o, where pip_i = pressure inside and pop_o = atmospheric pressure outside.
  • Let this pressure increase the radius from RR to R+dRR + dR.
R dR pi p = pi − po po
Liquid drop: excess pressure p=pi−pop = p_i - p_o
Derivation
  1. First surface area =4πR2= 4\pi R^2. When the radius becomes R+dRR + dR, the new area is:
    4π(R+dR)2=4πR2+8πR dR[dR2 neglected]4\pi(R+dR)^2 = 4\pi R^2 + 8\pi R\,dR \qquad [dR^2 \text{ neglected}]
  2. So the area grows by 8πR dR8\pi R\,dR. Work done = gain in surface energy = (gain in area) × surface tension:
    W=(8πR dR) S…(i)W = (8\pi R\,dR)\,S \qquad \text{…(i)}
  3. This work is also done by the excess pressure. Work = excess pressure × area × change in radius:
    W=p×4πR2×dR…(ii)W = p \times 4\pi R^2 \times dR \qquad \text{…(ii)}
  4. Equate (i) and (ii):
    p×4πR2×dR=8πR dR Sp \times 4\pi R^2 \times dR = 8\pi R\,dR\,S
Excess Pressure Inside a Liquid Drop pi−po=2SRp_i - p_o = \dfrac{2S}{R}
Excess Pressure: Soap Bubble

A soap bubble is a thin film. It has two free surfaces, one inside and one outside. So the real gain in surface area is doubled:

Total gain in area=2×8πR dR=16πR dR\text{Total gain in area} = 2 \times 8\pi R\,dR = 16\pi R\,dR

Equate the work done to the gain in surface energy:

p×4πR2×dR=16πR dR Sp \times 4\pi R^2 \times dR = 16\pi R\,dR\,S
pi po two surfaces
Soap bubble: a thin film with two surfaces
Excess Pressure Inside a Soap Bubble pi−po=4SRp_i - p_o = \dfrac{4S}{R}
Air Bubble Inside a Liquid

Inside a liquid, an air bubble behaves like a liquid drop in air. It has just one free surface. So the extra pressure inside it is:

Excess Pressure Inside an Air Bubble p=2SRp = \dfrac{2S}{R}
Note

Let an air bubble of radius RR be at a depth hh below the free surface of a liquid. The liquid has density ρ\rho and surface tension SS. Then the pressure inside the bubble is more than the atmospheric pressure by:

p=2SR+hρgp = \dfrac{2S}{R} + h\rho g

2.5Capillarity

Definition

Capilla is a Latin word. It means hair. A tube with a very fine bore, as thin as a hair, is called a capillary tube.

Dip a glass capillary in water: the water rises in it. Dip it in mercury: the mercury level falls in it. This rise or fall of a liquid in a capillary tube is called capillarity.

Water Mercury
Water rises in glass tubes (concave surface). Mercury falls (convex surface)
Some Examples
  • We use towels to dry our skin.
  • In trees, sap rises through fine vessels. This is like capillary action.
Capillary Rise
pa p0 A B h (a) r r θ θ R (b)
(a) Water rises by hh in a capillary. (b) Concave surface: radius of curvature rr, tube radius RR, angle of contact θ\theta
Setup — Given Information
  • A pressure difference exists across a curved liquid surface. One result of this is that water rises in a narrow tube (capillary) against gravity.
  • A capillary of radius RR is dipped in a vessel of water.
  • The water surface in the capillary becomes concave. So there is a pressure difference across the two sides of this surface (meniscus).
Derivation
  1. Let rr be the radius of curvature of the concave surface. From figure (b), r=Rsec⁡θr = R\sec\theta. The pressure pap_a on the air side is more than the pressure p0p_0 just below the surface:
    (pa−p0)=2Sr=2SRsec⁡θ=2SRcos⁡θ…(i)(p_a - p_0) = \dfrac{2S}{r} = \dfrac{2S}{R\sec\theta} = \dfrac{2S}{R}\cos\theta \qquad \text{…(i)}
  2. Points A and B are at the same level. By Pascal's law, they have the same pressure. So p0+ρgh=pap_0 + \rho g h = p_a, which gives:
    pa−p0=ρgh…(ii)[pa=atmospheric pressure]p_a - p_0 = \rho g h \qquad \text{…(ii)} \qquad [p_a = \text{atmospheric pressure}]
  3. From equations (i) and (ii):
    ρgh=2SRcos⁡θ\rho g h = \dfrac{2S}{R}\cos\theta
Height of Liquid Rise in a Capillary h=2Scos⁡θρRgh = \dfrac{2S\cos\theta}{\rho R g}

Liquids that wet glass (like water) rise in the capillary. Liquids that do not wet glass fall in it.

Blotting paper soaks up inkCapillarity
A towel soaks up waterCapillary action
03
Part 3

Hydrodynamics and Viscosity

The study of moving fluids is called hydrodynamics or fluid dynamics.

3.1Streamline, Laminar and Turbulent Flow

Streamline Flow
Definition

In streamline flow, every particle that reaches a given point moves exactly like the particle that passed there before it. It follows the same path and has the same velocity.

Definition

A streamline is a curve drawn in the flow. Its tangent at any point shows the direction of the fluid's velocity there.

A streamline is the path of a fluid particle in steady flow.

P Q v v path of a fluid particle
Velocity is along the tangent at every point
Properties of Streamlines
iThey Never Cross

Two streamlines can never cross. At a crossing point, a particle would have two directions of motion at once. Then the flow would not be steady.

iiCrowding Means Speed

Where the streamlines come closer together, the liquid moves faster. Where they are spread out, it moves slower.

PQR AB v1 v2 v3
A region of streamline flow
Laminar Flow

Sometimes a liquid flows over a horizontal surface as layers moving with different velocities. Such a flow is called laminar flow. No particle leaves its own layer to move into another. Laminar flow is usually a streamline flow.

Laminar flow: layers slide with different speeds
Turbulent Flow

In rivers and canals, the water may move very fast. The boundary surfaces may also cause sudden changes in velocity. Then the flow becomes irregular and disordered. Such a flow is called turbulent flow.

pillar
Turbulent flow: eddies form behind a pillar

3.2Equation of Continuity

Law

Equation of continuity: Let a non-viscous, incompressible fluid flow in a streamline way through a pipe whose cross-section changes. Then the product of the cross-section area and the fluid velocity (avav) is the same at every point of the pipe.

Setup — Given Information
  • A liquid of density ρ\rho flows through a tube AB. The liquid is non-viscous and incompressible. The cross-section of AB changes along its length.
  • At A: area a1a_1, velocity v1v_1.
  • At B: area a2a_2, velocity v2v_2.
v1 v2 a1 a2 v1Δt v2Δt AA′BB′
Fluid flow through pipe ABAB
Derivation
  1. In time Δt\Delta t, the mass of fluid entering at A and the mass leaving at B are:
    m1=a1v1Δt ρandm2=a2v2Δt ρm_1 = a_1 v_1 \Delta t\,\rho \quad\text{and}\quad m_2 = a_2 v_2 \Delta t\,\rho
  2. By conservation of mass, m1=m2m_1 = m_2. The fluid is incompressible, so ρ\rho stays the same:
    a1v1Δt ρ=a2v2Δt ρ  ⇒  a1v1=a2v2a_1 v_1 \Delta t\,\rho = a_2 v_2 \Delta t\,\rho \;\Rightarrow\; a_1 v_1 = a_2 v_2
Equation of Continuity a1v1=a2v2=av=constanta_1 v_1 = a_2 v_2 = av = \text{constant}

In a narrow part of the tube the fluid speeds up. In a wide part it slows down.

3.3Bernoulli's Theorem

Principle

Bernoulli's theorem: Take an incompressible, non-viscous fluid in streamline, irrotational flow. The total of its pressure energy, kinetic energy and potential energy, each per unit volume, is the same at every cross-section along the flow.

The theorem comes from the law of conservation of energy.

Bernoulli's Equation p+12ρv2+ρgh=constantp + \dfrac{1}{2}\rho v^2 + \rho g h = \text{constant}

pp = pressure energy, 12ρv2\tfrac{1}{2}\rho v^2 = kinetic energy, ρgh\rho g h = potential energy, all per unit volume (ρ\rho = density). Daniel Bernoulli gave it in 1738.

Setup — Given Information
  • The fluid is ideal, that is, non-viscous and incompressible. It has streamline flow through a pipe whose cross-section changes.
  • At A: pressure p1p_1, area a1a_1, velocity v1v_1, height h1h_1.
  • At B: pressure p2p_2, area a2a_2, velocity v2v_2, height h2h_2.
h1 h2 A B v1 p1 a1 v2 a2 p2
An ideal fluid flowing through a pipe whose cross-section changes
Derivation
  1. The pressure forces do net work on the fluid. Using a1v1=a2v2a_1 v_1 = a_2 v_2, this work is:
    W=(p1ρ−p2ρ)mW = \left(\dfrac{p_1}{\rho} - \dfrac{p_2}{\rho}\right)m
  2. This work increases the kinetic and potential energy of the fluid. The work-energy theorem then gives:
    p1ρ+12v12+gh1=p2ρ+12v22+gh2\dfrac{p_1}{\rho} + \dfrac{1}{2}v_1^2 + g h_1 = \dfrac{p_2}{\rho} + \dfrac{1}{2}v_2^2 + g h_2
Per Unit Volume p+12ρv2+ρgh=constantp + \dfrac{1}{2}\rho v^2 + \rho g h = \text{constant}
In Terms of Heads (÷ ρg) pρg+v22g+h=constant\dfrac{p}{\rho g} + \dfrac{v^2}{2g} + h = \text{constant}

Here pρg\dfrac{p}{\rho g} is the pressure head, v22g\dfrac{v^2}{2g} is the velocity head and hh is the gravitational head.

Note
Bernoulli's Equation for a Fluid at Rest

For a fluid at rest, v1=v2=0v_1 = v_2 = 0. So the velocity terms drop out:

p1−p2=ρg(h2−h1)p_1 - p_2 = \rho g (h_2 - h_1)
Limitations of Bernoulli's Theorem
  • Zero viscosity: it strictly holds only for non-viscous fluids.
  • Incompressible: the fluid must be incompressible. Its elastic energy is not counted.
  • Streamline only: it is not valid when the flow is turbulent or unsteady.

3.4Applications of Bernoulli's Theorem

Torricelli's Law: Speed of Efflux

The speed of efflux is the speed of a liquid coming out of a small hole (orifice) in a tank. The orifice is at depth hh below the free surface. Bernoulli's equation for the surface and the orifice gives:

Torricelli's Law v=2ghv = \sqrt{2gh}

Same speed as a body falling freely through height hh.

v1 pa pa A2 A1 2 1 h y1 y2
Liquid coming out of an orifice at depth hh
Venturimeter

A venturimeter (venturi tube) measures the flow speed of an incompressible fluid in a pipe.

This horizontal tube has a wide part (area a1a_1) and a narrow neck (area a2a_2). A manometer joins them. Continuity and Bernoulli's equation link the speed to the pressure difference:

p1−p2=12ρv12(a12a22−1)p_1 - p_2 = \dfrac{1}{2}\rho v_1^2\left(\dfrac{a_1^2}{a_2^2} - 1\right)
A (a1, v1) B (a2, v2) h liquid (ρm)
Venturimeter with a manometer
Atomizer or Sprayer

The atomizer is based on Bernoulli's principle. Pressing the bulb (the forward stroke of the piston) sends a fast stream of air past the top of the tube.

So the pressure there (p2p_2) is low. Atmospheric pressure (p1p_1) on the liquid pushes it up the tube. The liquid meets the fast air and breaks into a fine spray.

fast air p2 (low) p1 rubber bulb spray liquid
Atomizer (sprayer)
Aerofoil (Aircraft Wing) Lift

The wing of an aircraft has a special shape, called an aerofoil. Air flows faster over its top than along its bottom.

By Bernoulli's principle, the pressure above the wing is lower than below it. This pressure difference pushes the wing up. The upward force is called dynamic lift.

Lift high speed, low pressure low speed, high pressure
Air flow around a wing gives an upward lift
Spinning and Non-spinning Ball
Ball Without Spin

The air moves past the ball with the same speed above and below it. So there is no pressure difference. The ball feels no force up or down.

Same flow above and below: no lift
Ball With Spin

A spinning ball drags air with it. So the air speed is higher on one side of the ball. The resulting pressure difference bends its path into a curve. This is called the Magnus effect.

v F faster air, lower pressure slower air, higher pressure
Crowded streamlines above: net force upward

3.5Viscosity

Definition

Let one layer of a liquid move over the next layer. A tangential friction force then acts between them. This backward dragging force opposes their relative motion.

Viscosity is the property of a fluid that opposes the relative motion between its layers. It is also called fluid friction.

e.g. Machine parts get jammed in winter, because the lubricating oil becomes more viscous (thicker) in the cold.

Coefficient of Viscosity

Take a layer of fluid that is being deformed by a shearing stress. The coefficient of viscosity η\eta is the shearing stress divided by the rate of change of strain.

η=shearing stressrate of change of strain\eta = \dfrac{\text{shearing stress}}{\text{rate of change of strain}}
NQOR MP Δl = vΔt F v l
A fluid layer deformed by a shearing force
Coefficient of Viscosity η=F/Av/l=FlvA=FA dvdx\eta = \dfrac{F/A}{v/l} = \dfrac{Fl}{vA} = \dfrac{F}{A\,\dfrac{dv}{dx}}

where, FF = tangential force, AA = area of the layer, dvdx\dfrac{dv}{dx} = velocity gradient. Dimensions: [ML−1T−1][\mathrm{ML^{-1}T^{-1}}]

CGS Unit: Poise
1 poise=1 dyne s cm−21\ \text{poise} = 1\ \text{dyne s cm}^{-2}

η=1\eta = 1 poise when a tangential force of 11 dyne per cm² of area keeps a relative velocity of 1 cm s−11\ \text{cm s}^{-1} between two layers 11 cm apart.

SI Unit: Decapoise
1 decapoise=10 poise=1 N s m−21\ \text{decapoise} = 10\ \text{poise} = 1\ \text{N s m}^{-2}

The SI unit N s m−2\text{N s m}^{-2} (or Pa s) is also called the decapoise.

Fluid Friction Force (Viscous Force)

Between two fluid layers, the viscous force varies directly as the area AA of the layers. It also varies directly as the velocity gradient dvdx\dfrac{dv}{dx} between them.

Viscous (Fluid Friction) Force F=ηAdvdxF = \eta A \dfrac{dv}{dx}

where, η\eta = coefficient of viscosity, AA = area of the layers, dvdx\dfrac{dv}{dx} = velocity gradient. In vector form a minus sign is added. It shows that the force opposes the motion.

Area A dx v + dv v
Velocity gradient dvdx\dfrac{dv}{dx} between two fluid layers

3.6Critical Velocity

Definition

Critical velocity is the limiting speed of flow of a liquid. Up to this speed, the flow stays streamline. Above it, the flow becomes turbulent.

The critical velocity vcv_c of a liquid flowing in a tube depends on:

iViscosity

Coefficient of viscosity of the liquid (η)(\eta)

iiDensity

Density of the liquid (ρ)(\rho)

iiiRadius

Radius of the tube (r)(r)

Write vc=k ηaρbrcv_c = k\,\eta^a \rho^b r^c, where kk is a dimensionless constant. Comparing dimensions on both sides gives a=1a = 1, b=−1b = -1 and c=−1c = -1. So:

Critical Velocity vc=kηρrv_c = \dfrac{k\eta}{\rho r}

For streamline flow, vcv_c should be large. So η\eta should be large, and ρ\rho and rr should be small.

Tends to be Streamline

Liquids with high viscosity and low density, in narrow pipes.

Tends to be Turbulent

Liquids with low viscosity and high density, in broad pipes.

3.7Reynolds Number

Definition

The Reynolds number is a dimensionless number whose value tells whether the flow of a liquid in a pipe is steady (streamline) or turbulent. It was given by Osborne Reynolds (1842–1912).

Reynolds Number Re=ρvDηR_e = \dfrac{\rho v D}{\eta}

where, ρ\rho = density of the liquid, vv = its velocity, η\eta = its coefficient of viscosity, DD = diameter of the pipe

Re<1000R_e < 1000

The flow is streamline (laminar).

10001000 to 20002000

The flow is unsteady. It may switch between laminar and turbulent.

Re>2000R_e > 2000

The flow is turbulent.

Note

The Reynolds number at which turbulence just starts is called the critical Reynolds number. The Reynolds number compares two forces, each taken per unit area. It is the inertial force divided by the viscous force.

Re=Inertial forceForce of viscosityR_e = \dfrac{\text{Inertial force}}{\text{Force of viscosity}}

3.8Stokes' Law

Concept

Let a small sphere fall through a viscous fluid at rest. The fluid layers touching the sphere move along with it. The layers far away stay at rest. This relative motion produces a backward dragging (viscous) force that opposes the motion of the sphere.

Law

Stokes' law: A small sphere of radius rr moves with velocity vv through a fluid of viscosity η\eta. The backward dragging force on it is F=6πηrvF = 6\pi\eta r v. This law was given by Sir George G. Stokes (1819–1903).

Stokes' Law (Viscous Drag Force) F=6πηrvF = 6\pi\eta r v

Stokes worked out by calculation that the constant is k=6πk = 6\pi.

So the viscous drag depends on three things: (i) the coefficient of viscosity (η)(\eta) of the fluid, (ii) the velocity (v)(v) of the body and (iii) the radius (r)(r) of the spherical body.

Good to know
  • Examples: a falling raindrop, a swinging pendulum bob.
  • Applications: finding the charge of an electron (Millikan's oil-drop experiment), how clouds form and separate, and how a parachute works.

3.9Terminal Velocity

Definition

The terminal velocity is the maximum constant velocity that a body gains while falling through a viscous fluid.

A raindrop first speeds up as it falls. Its viscous force grows with speed. Soon its weight = upthrust + viscous force. From then on it falls at a constant (terminal) velocity.

Setup — Given Information
  • Let a sphere (radius rr, density ρ\rho) fall through a fluid of density σ\sigma and viscosity η\eta. Its terminal velocity is vv.
  • Weight of the sphere (downward) =43πr3ρg= \tfrac{4}{3}\pi r^3 \rho g
  • Upthrust = weight of fluid displaced (upward) =43πr3σg= \tfrac{4}{3}\pi r^3 \sigma g
  • Viscous force (upward, by Stokes' law) =6πηrv= 6\pi\eta r v
Derivation
  1. At terminal velocity, weight = upthrust + viscous force:
    43πr3ρg=43πr3σg+6πηrv\tfrac{4}{3}\pi r^3 \rho g = \tfrac{4}{3}\pi r^3 \sigma g + 6\pi\eta r v
  2. Keep the viscous term on one side:
    6πηrv=43πr3(ρ−σ)g6\pi\eta r v = \tfrac{4}{3}\pi r^3 (\rho - \sigma) g
Terminal Velocity v=29⋅r2(ρ−σ)gηv = \dfrac{2}{9}\cdot\dfrac{r^2 (\rho - \sigma) g}{\eta}

where, rr = radius of the body, ρ\rho = its density, σ\sigma = density of the fluid, η\eta = coefficient of viscosity

3.10Poiseuille's Formula

Concept

Poiseuille's formula gives the volume of liquid that flows each second through a narrow horizontal tube (capillary tube). The tube has length LL and radius rr. A pressure difference pp is applied across its ends.

Poiseuille's Formula V=Qt=πp r48ηLV = \dfrac{Q}{t} = \dfrac{\pi p\, r^4}{8\eta L}

where, pp = pressure difference across the ends, rr = radius of the tube, LL = length of the tube, η\eta = coefficient of viscosity

Rate of flow VV and radius of the tube (V∝r4)\left(V \propto r^4\right)Depends very strongly
Rate of flow VV and length (V∝1L)\left(V \propto \tfrac{1}{L}\right) and viscosity (V∝1η)\left(V \propto \tfrac{1}{\eta}\right)Inversely
End of Chapter 9 · notesshala.in
PDF 3.8 MB WhatsApp